2008 Herman Pines Award in Catalysis
Spring Symposium of the Catalysis Club of Chicago
 

 

 

Catalysis for Clean Diesel Power

Dr. Aleksey Yezerets
Cummins Inc.

ABSTRACT

 Despite extensive research in the area of alternative propulsion sources for ground transportation, such as fuel cells and hybrid electric systems, diesel engines remain the most promising solution for energy efficiency. This is due to their unparalleled power density and fuel/CO2 efficiency. Recent studies indicate that diesels represent more fuel-efficient option than gasoline-electric hybrids, except for light vehicles in a very congested urban driving.

Broader introduction of diesel engines in the US has been delayed by the increasingly stringent environmental regulations, such as 2007/2010 US EPA emissions standards. These are associated with a number of fundamental challenges for the respective catalytic emissions reduction systems, due to the necessity to selectively reduce NOx in the net oxidizing environment over a broad range of conditions, as well as poor reactivity of diesel soot towards oxidation under typical exhaust conditions. Furthermore, such systems need to be actively controlled, either continuously or in a periodic manner, based on their short-term history, long-term degradation factors, and driving conditions. This effectively leads to a need for sophisticated, often kinetic models-based control algorithms. Implementation of such active systems requires detailed quantitative understanding of their performance and degradation. It also often demands development of nontrivial gas analysis approaches, especially for the inherently non-steady-state, periodically operated devices.

Substantial progress in this area has recently culminated in commercialization of several diesel catalytic technologies; however the respective scientific and engineering challenges rapidly evolve and expand as well, driven by the ever tightening emissions regulations worldwide, on-board catalyst diagnostics requirements and ambitious goals for further fuel efficiency improvements.